Figure 3 Thermograms (mass loss - temperature) of organoplastics:
LBS-1 + 50 mass % Rusar-C, l = 1 (1);
LBS-1 + 60 mass % Rusar-C, l = 0.5 (2);
LBS-1 + 60 mass % Rusar-C, l = 1 (3);
LBS-1 + 60 mass % Rusar-C, l = 2 (4);
LBS-1 + 70 mass % Rusar-C, l = 1 (5)
Source: developed by the author
Table 8 Calculated kinetic parameters of the process of thermal destruction
Mathematical model of the process
R
S
.
10
-1
E
act.
, kJ/
mol
lg Z
PFR (LBS-1) + 60 mass.% of fiber Tanlon
kt = µ (1)
0.911
0.398
23.051
-2.057
kt =2µ
1/2
(2)
0.969
0.395
6.426
-2.799
kt = 2[ 1 - (1 -µ)
1/2
] (3)
0.966
0.462
30.054
-1.467
kt = 3 [1 - ( 1 - µ)
1/3
] (4)
0.964
0.483
32.671
-1.247
kt = -ln ( 1 - µ) (5)
0.960
0.524
38.342
-0.772
kt = 2[- ln(1 - µ)]
½
(6)
0.870
1.286
25.60
-1.159
kt = 3 [ -ln(1- µ)]
1/3
(7)
0.930
0.308
14.072
-2.158
1
2
3
4
5
kt = 4[ -ln (1- µ)]
¼
(8)
0.852
0.442
5.892
-2.544
kt = 1/2 µ
2
(9)
0.979
0.251
68.411
-0.268
kt=(1- µ)ln(1-µ) + µ (10)
0.976
0.991
64.897
0.461
kt = 3/2[1 - (1- µ
1/3
)
2
(11)
0.973
0.301
75.539
0.878
kt= [(1- µ)-(1-µ)
2/3
(12)
0.975
0.398
56.30
0.279
PFR (LBS-1) + 70 mass.% of fiber Tanlon
kt = µ (1)
0.310
0.537
13.457
-2.795
kt =2µ
1/2
(2)
0.937
0.658
66.171
-3.436
kt = 2[ 1 - (1 -µ)
1/2
] (3)
0.725
0.618
66.00
-1.987
kt = 3 [1 - ( 1 - µ)
1/3
] (4)
0.769
0.653
87.22
-1.664
kt = -ln ( 1 - µ) (5)
0.813
0.735
135.73
-0.929
kt = 2[- ln(1 - µ)]
½
(6)
0.668
2.540
170.21
-2.505
kt = 3 [ -ln(1- µ)]
1/3
(7)
0.800
3.480
51.95
-2.954
kt = 4[ -ln (1- µ)]
¼
(8)
0.921
3.860
75.41
-3.142
- 431 -